2-(2,5-Dimethoxyphenoxy)isoindoline-1,3-dione
نویسندگان
چکیده
In this work, the direct C-H functionalization reaction of 1,4-dimethoxybenzene with N-hydroxyphthalimide has been disclosed. A previously unknown product C-O coupling and was obtained. The proceeded under mild conditions, in which a commercially available manganese-based oxidizing agent used for generation phthalimide-N-oxyl radical. obtained compound is promising valuable precursor O-aryl hydroxylamine.
منابع مشابه
2-Methoxynaphthalene-1,4-dione
The title compound, C(11)H(8)O(3), was isolated from Impatiens balsamina plants (balsam, LIB) grown in our laboratory. The two six-membered rings of the naphthalene-1,4-dione unit are coplanar [maximum deviation = 0.009 (1) Å]. The O and C atoms of the meth-oxy substituent also lie close to the naphthalene plane, with deviations of 0.0090 (2) and 0.047 (2) Å, respectively.
متن کامل2-(2-Bromoethyl)isoindoline-1,3-dione
The asymmetric unit of the title compound, C(10)H(8)BrNO(2), contains three crystallographically independent mol-ecules. Two of the N-C-C-Br side chains adopt anti conformations [torsion angles = -179.8 (5) and -179.4 (4)°] and the other is gauche [-66.5 (6)°]. The crystal structure features short Br⋯O [3.162 (5) Å] contacts, C-H⋯O hydrogen bonds and numerous π-π stacking inter-actions [centroi...
متن کامل2-(2-Iodophenyl)isoindoline-1,3-dione
In the title compound, C(14)H(8)INO(2), the dihedral angle between the isoindole ring and the phenyl ring of the 1-iodo-benzene group is 84.77 (15)°. There is a short inter-molecular I⋯O contact of 3.068 (3) Å in the crystal.
متن کامل2-[2-(Methylsulfonyl)ethyl]isoindoline-1,3-dione
In the mol-ecule of the title compound, C(11)H(11)NO(4)S, the isoindoline ring system is almost planar with a maximum deviation of 0.008 (3)Å. In the crystal structure, inter-molecular C-H⋯O inter-actions link the mol-ecules into a three-dimensional network. π-π contacts between the isoindoline rings [centroid-centroid distances = 3.592 (1) and 3.727 (1) Å] may further stabilize the structure.
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ژورنال
عنوان ژورنال: Molbank
سال: 2022
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1514